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Re-downloading wasn't the problem, but I did figure out what was. I saw an icon for winzip on the german site that's hosting the file; so on a hunch, I tried using WinRAR to extract the information out of the the exe file. Worked like a charm.
I'm not sure why they would label an archive as an exec; but just to be through, I tried re-naming the file to "CrossFireReloaded_v102.rar" and win rar was able to detect the proper contents. Interestingly, winzip was unable to handle the archive. Go figure.
Thanks for your help guys; I would have given up long ago without it.